With thanks to both @k00b and @039802da15
For anyone following this, the correct cli command would be...
echo -n R | shasum -a 256 -t
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Echo adds a newline to the output, see https://stackoverflow.com/a/34430808
So your first command is actually hashing "R\n" while the 2nd one is hashing "R"
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@k00b and @039802da15
My thanks to you both (a bit of a 'head slap' moment for me!).
The cli echo commend is in fact directly from the Bitcoinmagazine feature, so I'm now thinking that it's an incorrect method. Time will tell, because if the checksum is not correct, a Wallet such as Sparrow will not accept the 24 Word Seed. I know that the Electrum Wallet does not do that check (I've tried it), so any random collection of 24 BIP0039 Seed Words will work.
Thanks again; back to it :)
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echo
appends a newline.>>> print(sha256('R\n'.encode('utf-8')).hexdigest()) 13b30eab8afdfab285103004686b2e6140ce53aa45a4f917341c740dfdb6e956
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$ echo R | shasum -a 256 -t
... returns...13b30eab8afdfab285103004686b2e6140ce53aa45a4f917341c740dfdb6e956
... while...print(sha256('R'.encode('utf-8')).hexdigest())
... returns...8c2574892063f995fdf756bce07f46c1a5193e54cd52837ed91e32008ccf41ac