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Yes, and it is worth noting that you cannot stop someone from paying this way. If someone sends you a transaction containing 100x 546 sat outputs what are you going to do? Call the police, say you've been robbed?
This scenario is exactly why legal tender laws usually have restrictions on how much of what denominations you can use to pay. If you try to pay with a few buckets full of pennies, the receiver absolutely can get the law involved on the basis of non-payment.
Paying with 100 546 sat outputs is no different.